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For the past two years, the defender has been playing on loan for West Ham in London, but last season he only played 15 games due to injuries.
Song arrived at Barcelona in 2012, after parting ways with Arsenal in London. He had signed a five-year contract, so before finally ending ties with the Catalans, it was still valid for another season.
Along with the arrival of the 28-year-old footballer, Rubin confirmed that they will strengthen their attack with Jonathan from Real Sociedad in San Sebastian.