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The attacker from Finland, Mikael Forssellas, will be among the substitutes during the Champions League quarter-final first leg match against Munich on Wednesday.
"Mikael will be on the bench. We do not have Robben, who is injured, and Kežman, who is disqualified," Mourinho told "Chelsea TV" on Monday.
Forssellas' loan agreement with Finland was terminated in January, and the player, who was on the injured list due to a knee injury since September, returned to Chelsea.
The 24-year-old Forssellas scored 17 goals in the Premier League last season, lifting Birmingham City to a respectable mid-table position and becoming the club's top scorer.
"He, the medical department, and the fitness trainers have done a great job together, giving the player a chance to do something good for the team," Jose Mourinho said at Stamford Bridge before Wednesday's match.
"I have to praise him because his attitude is fantastic. He is already valuable because of such strong determination."
