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Spanish champions Madrid "Atletico" will start the tournament with a match against "Rayo Vallecano", "Barcelona" will await "Elche", "Real" will face off against "Cordoba" players.
The first round will begin on August 23-24.
The highly anticipated first "El Clasico" match will be played on October 26 in Madrid, the second - on March 22 in Barcelona.
In the autumn clash, "Barcelona" fans still have hopes of seeing newcomer Luis Suarez, who may have his suspension reduced for biting Italian Giorgio Chiellini.